Research highlights

A smart new way to study mobile ions in perovskite solar cells

Researchers in the Hybrid Solar Cells group have developed a simple new method to study mobile ions in perovskite solar cells. These ions play a key role in the degradation of the cells, so understanding them is essential to make more stable solar devices.

This is an image of a perovskite crystal structure showing how the atoms are arranged. The purple and yellow octahedra represent groups of charged atoms, ions, built around a lead atom in the center. These clusters connect at their corners to form a repeating 3D pattern. The single yellow sphere in the middle represents a central positive ion and helps keep the structure stable.

Until now, studying mobile ions has been quite difficult. But in a new paper in ACS Energy Letters, first author Moritz Schmidt introduces an intuitive way to do this. The method works a bit like freezing and melting water. When water freezes, it stops flowing. In the same way, when we cool down a solar cell, the mobile ions stop moving.

“Before freezing, we push all the ions to one side of the cell”, says Moritz. “When the device warms up again, the ions start to flow, just like water melting from an ice cube. Because they are charged, their movement creates an electrical current that we can measure.” This approach reveals how many ions are present and how strongly they are bound in the material.

According to Bruno Ehrler, head of the Hybrid Solar Cells group, “The findings will enable many more researchers to study and quantify mobile ions. We expect that this will accelerate the improvements in the stability of perovskite solar cells.”

Learn more

If you have questions about this research, please contact Moritz Schmidt (m.schmidt@amolf.nl) or Bruno Ehrler (b.ehrler@amolf.nl).

On December 12 this paper was published online in ACS Energy Letters: “Quantification of mobile ions in perovskite solar cells with thermally activated ion current measurements.”

Read the full paper

Share article
What's happening

Most recent news items

All news items
Collaboration

Successful outcomes of international EBEAM program led by AMOLF

The EU Pathfinder project Electron Beams Enhancing Analytical Microscopy (EBEAM) that was recently completed has received a highly positive review of the European Innovation Council (EIC). EBEAM brought together eight European research institutions and companies, including AMOLF, that develop new concepts and instruments combining spectroscopic analysis with electron microscopy.

Read news item
Research highlights

Everything you need to know about organoids

Organoids are instrumental in improving our understanding of processes that are otherwise hidden inside the body. For instance, these small 3D organs can be used to test medicines on tissue grown from a patient’s own cells. AMOLF researchers carry out unique and complex experiments to follow organoids in time. In order to enable other researchers to benefit from their experiences, they now publish their methods in the prestigious journal Nature Protocols.

Read news item
Events and outreach

Minister Rianne Letschert wears hat and shoulder ornament inspired by Wim Noorduin’s research

This year at the opening of the parliamentary year (Prinsjesdag) Minister of Education, Culture and Science Rianne Letschert wears a spectacular hat and shoulder ornament. Both of them are inspired by the microscopic structures studied by group leader Wim Noorduin (AMOLF/UvA), which look remarkably like tiny flowers under a microscope. Artist and designer Malou Beemer translated these shapes, normally invisible to the naked eye, into wearable art.

Read news item
Nachi Stern, Group Leader Learning Machines at AMOLF
People and recognition

Nachi Stern awarded ERC Starting Grant to explore how matter learns

Why do brains learn, but rocks do not? Could a material one day adapt to its environment the way a living organism does? AMOLF group leader Dr. Nachi Stern has been awarded an ERC Starting Grant to investigate the physical laws of learning, in a project called, “Physical Learning in Dynamical Systems.”

Read news item
Stay informed

Get the latest research highlights, events, and news from our institute delivered to your inbox